The derivatives obtained had average degree of substitutions from 1.20 to 1.92 as determined by potentiometric back-titration. A multistep carboxymethylation was performed under heterogeneous reaction conditions, in isopropyl alcohol/water slurry medium, with aqueous sodium hydroxide solution for activation, and monochloroacetic acid for etherification. Carboxymethylation of kappa-carrageenan was attempted for the first time to synthesize derivatives with various degree of substitution. Many polysaccharide derivatives have been prepared by carboxymethylation reactions in order to increase the range of potential applications of these natural polymers in the chemical, food, pharmaceutical and cosmetic industries. International Nuclear Information System (INIS)Īranilla, Charito Tranquilan Nagasawa, Naotsugu Bayquen, Aristea V. Multi-step carboxymethylation of kappa-Carrageenan As conclusion, kappa carrageenan scan be potentially used for producing traditional foods based on the hard-texture-oriented foods whereas iota carrageenan can be used for the traditional foods with better adhesiveness. On the other hand, the reserve result were found in the adhesiveness parameter. The study indicated that traditional food models added kappa carrageenan at 2% generated remarkably higher in the hardness, cohesiveness, and springiness than those added iota carrageenan. hardness, cohesiveness, springiness and adhesiveness have been measured using texture analyzer. Therefore, the aim of this research was to determine the effect of kappa and iota carrageenans in traditional food models using modified cassava flour, sugar, and coconut milk. The carrageenan has not been widely applied to traditional foods. R.Ĭarrageenan has been known well as hydrocolloids that forming viscous dispersions and gels when dispersed in water. ![]() Published by Elsevier Ltd.Īpplication of iota and kappa carrageenans to traditional several food using modified cassava flourĪl-Baarri, A. DPEO in a mixed solution of kappa-carrageenan and iota- carrageenan suggested two possibilities for the microscopic network structure: an interpenetrating network structure, or micro-phase separation. The results of diffusion measurements for poly(ethylene oxide) (PEO) suggested that kappa-carrageenan formed thick aggregates that decreased hindrance to PEO diffusion by decreasing the solute kappa-carrageenan concentration in the voids of the aggregated chains, and that iota- carrageenan formed fine aggregates that decreased the solute iota- carrageenan concentration less. The results also suggested that longer carrageenan chains are preferentially involved in aggregation, thus resulting in a decrease in the average Mw of solute carrageenans. ![]() Rheological and NMR measurements suggested an exponential formation of rigid aggregates of kappa-carrageenan and a gradual formation of fine aggregates of iota- carrageenan during two step increases of G'. The temperature dependencies of the (1)H T2 and diffusion coefficient (D) of a mixed solution of kappa-carrageenan and iota- carrageenan were measured by NMR. NMR study on the network structure of a mixed gel of kappa and iota carrageenans. Then, the rheological experiments used to determine the small and large deformation behavior of gels will be detailed before reviewing the relationships between gel properties and hybrid carrageenan chemistry. After introducing the general chemical structure defining hybrid carrageenan, the isolation of the polysaccharide will be discussed focusing on the interplay between seaweed species, extraction parameters, and the hybrid carrageenan chemistry. ![]() This chapter focuses on hybrid carrageenan showing the ability to form gels in water, which is known in the food industry as weak kappa or kappa-2 carrageenan. This polysaccharide is extracted from specific species of seaweeds belonging to the Gigartinales order. Hybrid carrageenan is a special class of carrageenan with niche application in food industry. Hybrid carrageenans: isolation, chemical structure, and gel properties. Grounded mass concentration of some calcium salts for use in the composition of the jelly for sweet and savory dishes based on kappa-carrageenan The influence of the mass concentration of individual calcium for strength gels with different content kappa-carrageenan. Петро ВаÑильович ГурÑькийįull Text Available The influence of certain organic and mineral salts of potassium and calcium for strength gel kappa-carrageenan. Study Of Calcium And Potassium Different Nature Strength Gel Kappa-Carrageenanĭirectory of Open Access Journals (Sweden)
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Depending on the option you selected, Facebook will send you a code.Note- In case, your account has got hacked, you need to be extra quick in resetting your password as if the hackers get successful in removing your email address or phone number from your account and adding theirs, it will become almost impossible to recover your account. Select the one you can quickly access and then click ‘Continue’. Mainly, you need access to your email address or phone number associated with your Facebook account.You will see a list of account recovery options depending on the information you have added to your account.On the next page, enter the email address or phone number associated with your Facebook account, click ‘Search’. ![]() Go to and click on ‘Forgotten Password’.If you no longer remember the right password, recover your account using Facebook’s sign-in page: Note- This article aims to help users in recovering a Facebook account on the desktop as well as using the Facebook Mobile App. So if you are one of them, go through the article provided below to get comprehensive information about the Facebook password recovery process. Every now and then, millions of users keep losing access to their Facebook accounts for several reasons. 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Reign announced the position while a guest on musician Dave Navarro's radio show, Dark Matter, citing her background in music appreciation courses at UCLA. In March 2012, indie rock magazine and website Rock Confidential brought Reign on as a weekly music reviewer, dubbed "The World's Hottest Music Critic". Hard Reign (2016), Elegant Angel, dir.Deep Inside Tasha (2014), Reign Productions, dir.Tasha Reign Is Sexy (2012), Reign Productions.She performed her first anal scene in November 2012, with Peter North.Also in 2012, Reign launched her official membership site, Reign also appeared on the cover along with an interview and photo spread in France's Hot Video adult industry trade magazine and was their red carpet correspondent conducting interviews at the 28th annual XRCO Awards. The 2012 XBIZ Awards enlisted Reign for the position of Trophy Girl, along with fellow adult star Bibi Jones. Her adult movie highlights include filming superhero porn in Japan, starring in New Sensations' Anchorman: A XXX Parody, and appearing on the covers of many adult releases, including Zero Tolerance Entertainment's Kittens & Cougars 5 and Knockers Out, as well as Pleasure Dynasty's Zorro XXX: A Pleasure Dynasty Parody. She has worked with production companies such as Third Degree Films, Adam & Eve, Brazzers, Digital Playground, Elegant Angel, Evil Angel, Girlfriends Films, Hustler Video, Jules Jordan Video, New Sensations, Penthouse Video,, Twistys, Vivid Entertainment, Wicked Pictures, X3Sixty Network, and Zero Tolerance Entertainment. Playboy (U.S.) October 2010, as Rachel LorraineĪfter signing with adult industry talent agency LA Direct Models, Reign filmed her first adult movie in 2010 at the age of 21, a girl-girl scene for the production company Lethal Hardcore.Additional magazines Reign covered include Club, Xtreme, and Hot Vidéo. In February 2013 she appeared on the cover of OC Weekly. She appeared as a centerfold model in the April 2011 issue of Penthouse and the following month she was the Penthouse Pet of the Month. While enrolled as a student at UCLA, Reign was selected by Playboy magazine for its 2010 "Girls of the Pac-10" issue, as well as the magazine's "Cyber Girl of the Week". 4 Big boob movies / pictures of Tasha ReignĪ former Hooters Girl, she began her career as a professional stripper in 2008, dancing at a club called the Silver Reign, from which she took her pseudonym.When using a search engine such as Google, Bing or Yahoo check the safe search settings where you can exclude adult content sites from your search results Īsk your internet service provider if they offer additional filters īe responsible, know what your children are doing online. Use family filters of your operating systems and/or browsers Other steps you can take to protect your children are: More information about the RTA Label and compatible services can be found here. Parental tools that are compatible with the RTA label will block access to this site. We use the "Restricted To Adults" (RTA) website label to better enable parental filtering. Protect your children from adult content and block access to this site by using parental controls. PARENTS, PLEASE BE ADVISED: If you are a parent, it is your responsibility to keep any age-restricted content from being displayed to your children or wards. Furthermore, you represent and warrant that you will not allow any minor access to this site or services. This website should only be accessed if you are at least 18 years old or of legal age to view such material in your local jurisdiction, whichever is greater. You are about to enter a website that contains explicit material (pornography). ![]() See or store associate for more details.Ĭurbside orders must be picked up two hours prior to store closing time. Prices & selection may vary in stores & online. While delivery is contact-free, be sure to be home during your delivery window to bring any perishable items inside right away. Delivery may be delayed due to acts beyond our reasonable control, which may include, but are not limited to, weather, strikes, power outages, shutdowns, local, provincial or federal governmental actions, and other similar acts. Orders placed after 3pm will be fulfilled the next day. Order by 9am for delivery between 12pm-3pm, by 1pm for delivery between 3pm-6pm, & by 3pm for delivery between 6pm-8pm. Same-day delivery is available in most areas. Offer valid on .įree Same-Day Delivery offer valid on select merchandise purchased at when choosing Same-Day Delivery. Terms and conditions of this offer are subject to change at the sole discretion of PetSmart. Offer may not be combinable with other promotional offers or discounts. Offer not valid on all or select products in the following categories: live pets, canned, fresh or frozen foods, select cat litters. states, military APO/FPO addresses and select areas throughout Canada. Valid only on orders shipped within the contiguous 48 U.S. Due to size and/or weight, certain items bear an additional shipping surcharge or special handling fee. Savings will automatically reflect in shopping cart with the purchase of qualifying merchandise. Transaction total is prior to taxes & after discounts are applied. Must be signed into your Treats account prior to purchase. Treats members enjoy Free Standard Shipping on select orders over $49. Terms and conditions of this offer are subject to change in the sole discretion of PetSmart. Quantities may be limited and deliveries may be delayed. Treats members receive free shipping on select orders over $49.00, prior to taxes & after discounts are applied. Savings will automatically reflect in shopping cart with purchase of qualifying product and enrollment in Autoship. Must be signed in to your Treats account to receive discount. Certain products and brands are not eligible for sitewide offers or promotions and specifically excludes: select products from The Pharmacy at PetSmart, all Royal Canin and Eukanuba products, all services, give cards, gift certificates, previous purchases and charitable donations. Save 35% on your first Autoship order up to a maximum savings of $20.00 and 5% on all recurring orders. Limited to one time per customer during the offer period. ![]() Offer may not be combined with other promotional offers or discounts and specifically excludes any available Autoship offers. Offer not valid on services, gift cards, gift certificates, previous purchases, charitable donations, and may exclude all or select items from various brands. Discount taken off highest priced qualifying item in cart. Offer valid with Treats membership online only at or on the app. Save $10 off your first purchase of $50 or more in Pharmacy. Savings will automatically reflect in shopping cart with purchase of qualifying product. Offer not valid on veterinary care, services, gift cards, gift certificates, previous purchases & charitable donations. See product page to determine eligibility. Save 20% online only for merchandise on or the PetSmart app. ![]() At the time, only Robinho (£32.5m) had cost the Premier League side more.ĭzeko's first goal for the club was a late equaliser to prevent an embarrassing defeat by Notts County in the fourth round of the FA Cup. He was the 13th best player in the world 14 years ago and now he's still scoring important goals." Dzeko has contributed nine goals and five assists across 50 matches for Inter this season "In the 2009 Ballon d'Or rankings he finished 13th," added Laurens. Nicknamed the 'Bosnian Diamond', Dzeko would score 85 goals in 142 appearances for Wolfsburg helping the German side lift the Bundesliga title in 2009 for the first time in the club's history. ![]() Then a creative midfielder he would soon move to Czechian outfit FK Teplice and then on to Felix Magath's Wolfsburg in 2007. He leads the front line perfectly." From Sarajevo to Serie A Dzeko scored 26 goals in all competitions as City won the Premier League in 2013-14, but he was loaned to Roma two seasons laterĭzeko, who grew up in Sarajevo during the Bosnian war, began his football career in 2003 at local side Zeljeznicar. "He is dedicated to the game, disciplined, looks after himself immaculately. "It is no surprise to me he is doing this, having known him for 15 years. "He is a world class player," he told BBC Radio 5 Live. Of the 18 players in City's squad from that famous day against QPR 11 years ago, only goalkeeper Joe Hart and midfielder James Milner were still playing Champions League football this season.įormer international team-mate Asmir Begovic puts Dzeko's agelessness down to his excellent work ethic. I still don't know at 37 how you can be so influential in such a big game. "It's the same with Ibra and Paolo Maldini and all of those guys. "I just think the longevity, it's very rare to still be able to play at this level, after being so good so long ago, and still have an impact," said European football expert Julien Laurens. Without Dzeko, though, there would be no Aguero moment. Minutes later, and thanks to Sergio Aguero's legendary winner, City lifted their first Premier League title. Trailing Queens Park Rangers 2-1 on the final day of the 2011-12 season, Dzeko rose highest to head home a dramatic 92nd-minute leveller. He is involved all the time." No Aguero moment without Dzeko Dzeko scored 72 goals in 189 appearances for Manchester City with his header against Queens Park Rangers in 2012 arguably the most important of his careerĭzeko may still be scoring well into his 38th year, but City fans will always remember him for one particular finish. ![]() "He is a very technically gifted footballer, he can come short and play as a number 10. "He's a very intelligent football player, he has a finesse about him as well," said Italian football expert James Horncastle on BBC Radio 5 Live. Across both legs his work-rate and hold-up play continuously created chances for team-mates. What a finish, a cracker!"ĭzeko's goal kickstarted Inter's 3-0 aggregate win. "It was behind him, you expect him to take a touch but he guides it. "There are so few top strikers in the world that score that type of goal," former Scotland forward Pat Nevin told BBC Sport. Hakan Calhanoglu chipped in a corner which Bosnian Dzeko had the presence of mind, and quality, to meet with a hooked left-footed volley into the top corner. 'He is involved all the time' Edin Dzeko (37 yrs 54 days) is the second oldest player to score in a Champions League semi-final, after Ryan Giggs (37 yrs 148 days) for Manchester United vs Schalke in 2010-11Īfter all the build-up, Inter needed just eight minutes to take the lead against AC Milan in their Champions League semi-final first leg. 'Guardiola's voodoo will end Man City's hoodoo' - Noel Gallagher.Fan reaction: 'I saw City lose at York.Shearer column: 'Man City have set the standard - how can Man Utd catch up?'.If anyone can stop Pep Guardiola's all-conquering side, it might just be the "intelligent", "influential" forward out to seek revenge on his former club. For Inter, the striker could cap off his star-studded career with a Champions League winners' medal having already scored the crucial opener in his side's semi-final win over bitterest rivals AC Milan. So, as you experiment with how different components are powered, keep in mind that the power does not have to be continuous. Redstone signals pass at the rate of 10 ticks per second.īy controlling the speed of the ticks, you can control the speed at which a component does something. In Minecraft, the term for time passing is "ticks" and time passes at 20 ticks per second. Power can also travel in pulses called "ticks" and there are ways to vary the rate. Power from a redstone torch is continuous. For example, putting a redstone torch on top of a piston will not power it, but placing a redstone block on top of a piston will power it.Ī redstone torch can be deactivated by powering the block it is placed on. Redstone torches don't power the block they're on. Placing the torch or block in front of the piston will not power it. The redstone torch or redstone block must be next to or below the piston to power it. Placing a redstone torch on a powered block will deactivate the block. Power radiates out from a redstone torch in all directions, as shown in this grid that is powered by one redstone torch.Ī redstone torch powers the block above it, takes redstone signal from it, and powers all adjacent redstone components including above and below the torch.Ī redstone torch will not power the is block it is placed on.Redstone blocks and redstone torches each have a signal strength of 15.A blob of redstone dust will power all the blocks around it and the block it is placed on.Random redstone dust, torch, and block facts, in no particular order You could also add another redstone torch to boost the power. Place another piston next to the glowing part of the redstone. The pistons won't do anything if the signal is too weak to make the redstone touching the piston glow. Give yourself a piston and place it anywhere around the dark end of the redstone line. Notice that the glow gets fainter as you get farther from the torch. Place more redstone dust to continue the line in one direction. The redstone blob will glow and align itself to point towards the torch. Place one handful of redstone dust dust on the ground. Give yourself redstone dust and a redstone torch. The redstone signal coming out of a power source starts at 15 and decreases by 1 for each block the line of redstone dust is extended. As the power signal travels farther from the power source, it gets weaker at a predictable rate. Redstone dust acts like a conduit between a power source and a component. Placing a redstone block on the lamp will power it. Putting the torch on the lamp itself will not power it. You can power most redstone devices, like a redstone lamp, by putting a redstone torch on an adjacent block. Using redstone torches, redstone blocks, and redstone dust As with electrical circuits, it's possible to build incredibly sophisticated machines based on the combination of simple connections and switches among components. What is redstone? Redstone is kind of like electrical circuits within Minecraft. This guide assumes that you know how to make a flat, creative-mode world and how to give yourself the things you need, like redstone dust and pistons. ![]() It's recommended that the following be completed before beginning this tutorial: Basic redstone components and how they work.We reserve the right to make additions, deletions, or modification to the contents on the Service at any time without prior notice. In no event shall we be liable for any special, direct, indirect, consequential, or incidental damages or any damages whatsoever, whether in an action of contract, negligence or other tort, arising out of or in connection with the use of the Service or the contents of the Service. We assume no responsibility for errors or omissions in the contents on the Service. The information contained on this website, cubical.xyz(the "Service"), is for general information purposes only. The name “Minecraft” as well as related names, marks, emblems and images are registered trademarks of Mojang. The official Minecraft website can be found at. Cubical.xyz is not affiliated, associated, authorized, endorsed by, or in any way officially connected with Minecraft or Mojang, or any of its subsidiaries or its affiliates. ![]() This means the MySQL root account and its password.
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